Advanced Technology Recovers 98% of Oil in Produced Water | SLB

Advanced media technology recovers 98% of emulsified heavy oil from produced water, enabling reinjection

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Europe, Onshore

An operator used an oil-water separator, advanced regenerative water treatment media, and advanced media polisher filters to remove fluctuating high concentrations of asphaltene-laden oil, diesel-range organics, and suspended solids from produced water. Cleaning the water enabled its reinjection and use for enhanced oil recovery (EOR).

Clean produced water for reuse in EOR campaign

A major oil operator was generating 15,000 bbl of produced water per day during heavy oil production in its operation in southeastern Europe. The produced water included diluents that emulsified the oil, leaving high concentrations of asphaltenes and diesel-range organics with total suspended solids (TSS) concentrations up to 800 mg/L. Oil, grease, and emulsion content varied greatly during production. The corrosive nature of the produced water necessitated the use of 316 stainless steel construction material on the project. The operator sought a solution that would enable filtering the water to less than 10 ppm of contaminants, which would allow reinjection of the produced water for reuse in the operation.

Deploy robust three-stage advanced media technology solution

SLB recommended that the operator include advanced media technology in the treatment train to reduce oil content from the original 2,500 ppm to less than 10 ppm. The system included three stages of decontamination:

  • The primary stage incorporated an oil-water separator to coalesce and recover heavy oil droplets ranging from 100 to 2,500 ppm.
  • The secondary stage used the advanced regenerative water treatment media to treat dispersed and emulsified heavy oil present at 1,000 ppm and TSS up to 800 mg/L.
  • The tertiary stage used the advanced media polisher filters to reduce oil contamination to less than 10 ppm.

The advanced media technology system included automatic controls to respond to fluctuations in flow rates and pressure drop. Because of the risk of corrosion posed by the produced water, anodic protection was used to maintain system integrity.

Achieved 2-ppm water filtration for reinjection

By using advanced media technology, the operator effectively and consistently removed contaminants from the produced water to achieve a 2-ppm level for reinjection use—lower than the 10-ppm level that was specified. This performance was well maintained during large fluctuations of asphaltene and diesel-range organics in free, dispersed, and emulsified phases. Inlet oil levels varied between 100 and 2,500 ppm, and the system outlet showed oil reduced to 10 ppm or less throughout use of the system.

Water samples from different stages of treatment show progressively less hydrocarbons and solids.
In this sample, the coalescing separator outlet first cleaned the 720-ppm oil-laden produced water to 150 ppm. Then, the advanced regenerative water treatment media cleaned the water to 20 ppm and the advanced media polisher filter, the third and final stage, further cleaned the water to 2 ppm, which is far lower than the 10-ppm level that the operator originally specified.
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